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Atlético took the lead through Giovanni Simeone in the 39th minute, but Barcelona quickly responded with an equaliser from Marcus Rashford just three minutes later.
Substitute Robert Lewandowski netted the decisive goal in the 87th minute, capitalising on Atlético’s numerical disadvantage after Nico González was sent off before halftime.
The win keeps Barcelona firmly at the top, while Atlético Madrid remain fourth on 57 points, just one point behind Villarreal.
The match served as a preview of the upcoming Champions League quarter-final, where the two sides will meet again at Camp Nou for the first leg.