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Vinícius struck in the 55th and 66th minutes to secure the victory and delay Barcelona’s title celebrations.
The win reduced the gap between second-placed Real Madrid and league leaders Barcelona to 11 points, with four matches remaining. Both teams are set to meet in a highly anticipated El Clásico next weekend.
The upcoming match at Camp Nou could prove decisive, as a victory for Barcelona would secure their 29th league title and second consecutive championship, while a win for Real Madrid would keep their slim hopes alive of claiming a 37th La Liga title.
Real Madrid sit second with 77 points, while Barcelona lead with 88. Espanyol remain 13th with 39 points.