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The match, played at the Carlos Belmonte Stadium, marked a disappointing first game in charge for new head coach Álvaro Arbeloa, who was appointed earlier this week following Xabi Alonso's dismissal. Albacete secured a historic victory with a stoppage-time winner from Giefte Bentancur, who struck in the 90+4 minute after having already given his side the lead earlier in the second half.
Real Madrid, missing several first-team regulars, including Kylian Mbappé, struggled throughout the encounter. Goals from Franco Mastantuono and Gonzalo García were not enough to prevent elimination, despite a late equaliser deep into stoppage time.
The defeat came days after Real Madrid lost the Spanish Super Cup final to rivals Barcelona, prompting president Florentino Pérez to turn to Arbeloa.